110612-23-2

Basic information

• Product Name: (2S,3R,4S,5S)-5-Ethyl-6-methyl-4-phenylselanyl-2-((1R,3aS,3bR,5aS,6aS,9aR,10aS,10bS,12aS)-8,8,10a,12a-tetramethyl-hexadecahydro-7,9-dioxa-dicyclopenta[a,h]phenanthren-1-yl)-heptan-3-ol
• CAS NO: 110612-23-2
• Molecular Weight: 643.853
• Mol File: 110612-23-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3R,4S,5S)-5-Ethyl-6-methyl-4-phenylselanyl-2-((1R,3aS,3bR,5aS,6aS,9aR,10aS,10bS,12aS)-8,8,10a,12a-tetramethyl-hexadecahydro-7,9-dioxa-dicyclopenta[a,h]phenanthren-1-yl)-heptan-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4S,5S)-5-Ethyl-6-methyl-4-phenylselanyl-2-((1R,3aS,3bR,5aS,6aS,9aR,10aS,10bS,12aS)-8,8,10a,12a-tetramethyl-hexadecahydro-7,9-dioxa-dicyclopenta[a,h]phenanthren-1-yl)-heptan-3-ol(110612-23-2)
• EPA Substance Registry System: (2S,3R,4S,5S)-5-Ethyl-6-methyl-4-phenylselanyl-2-((1R,3aS,3bR,5aS,6aS,9aR,10aS,10bS,12aS)-8,8,10a,12a-tetramethyl-hexadecahydro-7,9-dioxa-dicyclopenta[a,h]phenanthren-1-yl)-heptan-3-ol(110612-23-2)

Safety Data

• Hazardous Substances Data: 110612-23-2(Hazardous Substances Data)

Upstream product

• 110556-80-4 Methanesulfonic acid (3S,5S,8R,9S,10S,13R,14S,17R)-17-((E)-(1R,4S)-4-ethyl-1,5-dimethyl-hex-2-enyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-3-yl ester 
• 110556-81-5 (24S)-2α,3α-isopropylidenedioxy-5α-stigmast-22(E)-ene 
• 1666-13-3 diphenyl diselenide 
• 110556-82-6 (22R,23R)-22,23-epoxy-2α,3α-isopropylidenedioxy-5α-stigmastane 
• 20817-72-5 (22E)-stigmasta-4,22-dien-3-one 
• 4736-56-5 (24S)-5α-stigmast-22(E)-en-3β-ol 
• 83-48-7 Stigmasterol 

Relevant articles and documents

Synthesis of 6-Deoxohomodolichosterone, a New Plant-growth-promoting Steroid

6-Deoxohomodolichosterone (1), a new member of the brassinosteroid family, was synthesized in twelve steps from stigmasterol (4).Birch reduction of the dienone (5) gave directly 5α-stigmast-22-en-3β-ol (6), the mesylate of which was treated with lithium bromide in refluxing dimethylformamide.Selective oxidation of the 2-ene function of the resulting 2,22-diene (7), followed by acetonide formation, provided the acetonide 22-alkene (8).Epoxide-ring opening of the (22R,23R)-epoxide (9), derived from (8), with phenylselenolate anion, treatment with 30percent hydrogen peroxide, and epoxidation with peracid afforded the 22-hydroxy-23,24-epoxide (15).Ready cleavage of the epoxide ring of compound (15) with aluminium isopropoxide and deprotection yielded 6-deoxohomodolichosterone (1).