110614-58-9Relevant academic research and scientific papers
Generation and reactions of metal-free trialkylgermyl anions from silylgermane and digermane
Mochida, Kunio,Suzuki, Hiroyasu,Nanba, Michihiko,Kugita, Tsuyoshi,Yokoyama, Yasuo
, p. 83 - 88 (2007/10/02)
Metal-free trimethylgermy) anions were prepared by cleavage of the Ge-Si bond of (trimethylsilyl)trimethylgermane and the Ge-Ge bond of hexamethyldigermane with tetrabutylammonium fluoride (TBAF) in hexamethylphosphoric triamide (HMPA).The reactions of metal-free germyl anions produced by a catalytic or one-equivalent amount of TBAF with organic halides carbonyl compounds, and α,β-unsaturated ketones were examined.Keywords: Silicon; Germanium; Germyl anions; Tetrabutylammonium fluoride; Organic halides; Group 14
Trimethylgermylation of ketones
Inoue, Sumie,Sato, Yoshiro
, p. 2568 - 2570 (2008/10/08)
Treatment of lithium enolates of ketones with chlorotrimethylgermane gave preferentially α-trimethylgermyl ketones in hexane.
