110622-50-9

Upstream product

• 108934-87-8 N,N-dimethyl-4-nitrobenzene-sulfenamide 

Downstream Products

• 110622-51-0 anti-7-(4-nitrophenylthio)bicyclo<2.2.1>hept-exo-2-yl N,N-dimethylsulfamate 
• 110622-51-0 syn-7-(4-nitrophenylthio)bicyclo<2.2.1>hept-exo-2-yl N,N-dimethylsulfamate 
• 108934-89-0 exo-5-(p-nitrophenylthio)tricyclo<2.2.1.0^2,6>heptan-endo-3-ol dimethylsulfamate 
• 112128-64-0 γ-lactone of exo-5-(4-nitrophenylthio)-endo-6-hydroxy-endo-3-methoxycarbonylbicyclo<2.2.1>heptane-endo-2-carboxylic acid 

Relevant academic research and scientific papers

SULFONATE-ACTIVATED OPENING OF THE CYCLOPROPANE FRAGMENT OF QUADRICYCLENE

The chlorosulfoamines and 4-nitrobenzenesulfenyl sulfamates produced by the reaction of N-chlorodialkylamines and N,N-dialkylsulfenamides with sulfur trioxide react readily with quadricyclene with opening of one of the cyclopropane rings.The structure of

ELECTROPHILIC SULFAMATOSULFENYLATION OF OLEFINS

The reaction of N,N-dialkylarenesufenamides with sulfur trioxides gave arenesulfenyl sulfamates, which have clearly defined electrophilic characteristics.These reagents are capable of adding at the C=C bond of olefins with the formation of the sulfamates of arylthio-substituted alcohols.The reaction with cyclohexene is stereospecific and leads to the trans-1,2-adducts, while the reaction with norbornene and norbornadiene is accompanied by rearrangement of the carbon framework.For the case of the cyclohexane derivatives it was shown that the vicinal arylthiosulfamates are highly sensitive to nucleophilic reagents.