110624-99-2Relevant academic research and scientific papers
Studies on Selected Transformations of Some Fluoromethanephosphonate Esters
Blackburn, G. Michael,Brown, David,Martin, Stephen J.,Parratt, Martin J.
, p. 181 - 186 (2007/10/02)
The thermal stability of α-fluoromethanephosphonate carbanions decreases in the series CHF>CF2>CFCl.Acylation products of the difluoromethanephosphonate carbanion show high electrophilic reactivity which results in the inmediate formation of secondary products.This behaviour is not observed for the monofluoromethanephosphonate carbanion.Attemps to acylate or phosphorylate the chlorofluoromethanephosphonate carbanion unexpectedly provide esters of fluoromethylenebisphosphonic acid as products.Some physical characteristics of fluoromethanephosphonic acids are described.
