110658-00-9

Basic information

• Product Name: trans-1,2-diphenyl-1,2-dihydrobenzocyclobutene
• CAS NO: 110658-00-9
• Molecular Weight: 256.347
• Mol File: 110658-00-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-1,2-diphenyl-1,2-dihydrobenzocyclobutene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1,2-diphenyl-1,2-dihydrobenzocyclobutene(110658-00-9)
• EPA Substance Registry System: trans-1,2-diphenyl-1,2-dihydrobenzocyclobutene(110658-00-9)

Safety Data

• Hazardous Substances Data: 110658-00-9(Hazardous Substances Data)

Upstream product

• 13209-15-9 1,2-bis(dibromomethyl)benzene 

Relevant articles and documents

Reaction of trialkyl(dibromomethyl)silanes or 1,2-bis(dibromomethyl)benzene with triorganomanganates. A facile and selective synthesis of alkenylsilanes and 1,2-diaryl-1,2-dihydrobenzocyclobutenes

Treatment of trialkyl(dibromomethyl)silanes with trialkylmanganates, derived from manganese(II) chloride and three molar amounts of Grignard reagents or alkyllithiums, provided (E)-1-trialkylsilyl-1-alkenes with high stereoselectivity in good yields. The reaction of trialkyl(dibromomethyl)silanes with alkylmagnesium halides proceeded in the presence of a catalytic amount of manganese(II) chloride. Treatment of 1,2-bis(dibromomethyl)benzene with triphenylmanganate gave 1,2-diphenyl-1,2-dihydrobenzocyclobutene.