110672-48-5

Upstream product

• 52188-74-6 (2Z,6Z)-8-(benzyloxy)-2,6-dimethylocta-2,6-dien-1-ol 
• 110672-46-3 O-((2E,6Z)-8-Benzyloxy-2,6-dimethyl-octa-2,6-dienyl)-N,N-dimethyl-hydroxylamine 
• 83110-43-4 ((Z)-6-Chloro-3,7-dimethyl-octa-2,7-dienyloxymethyl)-benzene 
• 110672-38-3 ((Z)-6-Benzyloxy-1-isopropenyl-4-methyl-hex-4-enyl)-dimethyl-amine 
• 86636-47-7 (2Z,6Z)-8-(benzyloxy)-2,6-dimethyl-1-(tetrahydropyran-2-yloxy)-octa-2,6-diene 
• 55802-98-7 (2Z)-1-(benzyloxy)-3,7-dimethylocta-2,6-diene 

Downstream Products

• 81757-27-9 (2E,6E)-8-(benzyloxy)-2,6-dimethylocta-2,6-dienal 

Relevant academic research and scientific papers

Regio- and Stereo-selective Oxidation of gem-Dimethyl Olefins via -Sigmatropic Rearrangement of Allyl Amine Oxides

Highly regio- and stereo-selective oxidation sequences are described for the efficient conversion of the gem-dimethyl olefin terminus of acyclic terpenes to terminal trans-allylic alcohols and trans α,β-unsaturated aldehydes.

STEREOSELECTIVE SYNTHESIS OF A CISOID C10 ISOPRENOID BUILDING BLOCK AND SOME ALL-CIS-POLYPRENOLS

As the key compound for the construction of cisoid terpenoids, (2Z,6Z)-8-benzyloxy-1-chloro-2,6-dimethylocta-2,6-diene was sinthesized stereoselectively via the Wittig reaction starting from nerol.The ten-carbon building block was coupled with prenyl or neryl p-tolyl sulfone to afford, after reductive desulfonylation, (Z,Z)-farnesol and (Z,Z,Z)-nerylnerol, respectively.