110684-48-5

Basic information

• Product Name: Benzenamine, 4-methyl-N-(3-pyridinylmethylene)-
• CAS NO: 110684-48-5
• Molecular Formula: C13H12N2
• Molecular Weight: 196.252
• Mol File: 110684-48-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-methyl-N-(3-pyridinylmethylene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-methyl-N-(3-pyridinylmethylene)-(110684-48-5)
• EPA Substance Registry System: Benzenamine, 4-methyl-N-(3-pyridinylmethylene)-(110684-48-5)

Safety Data

• Hazardous Substances Data: 110684-48-5(Hazardous Substances Data)

Upstream product

• 106-49-0 p-toluidine 
• 500-22-1 3-pyridinecarboxaldehyde 

Downstream Products

• 415678-24-9 4-N-p-methylphenylamino-4-[β-pyridyl]-1-butene 
• 113248-79-6 C₁₃H₁₄N₂ 
• 110684-30-5 3-(3-p-Tolyl-3H-[1,2,3]triazol-4-yl)-pyridine 
• 110684-11-2 3-(3-p-Tolyl-4,5-dihydro-3H-[1,2,3]triazol-4-yl)-pyridine 

Relevant articles and documents

2,5-Bis(azulenyl)pyrrolo[3,2-b]pyrroles-the key influence of the linkage position on the linear and nonlinear optical properties

The first route towards pyrrolo[3,2-b]pyrroles containing two azulene moieties at positions 2 and 5 was developed. The key step of this approach is the three-step transformation of pyridine scaffolds into azulene via sequential N-arylation followed by ring-opening and a reaction with cyclopentadiene. The resulting quadrupolar acceptor-donor-acceptor compounds possess interesting optical properties such as bathochromically shifted absorption with the magnitude of the red-shift strongly dependent on the linkage position. Two-photon absorption of these functional dyes is markedly different from that of previously described pyrrolo[3,2-b]pyrroles. The experimental optical spectra were rationalized using time-dependent density functional theory calculations of both the linear and nonlinear optical properties.

Sulfonic acid supported on hydroxyapatite-encapsulated-γ-Fe 2O3 nanocrystallites as a magnetically separable catalyst for one-pot reductive amination of carbonyl compounds

A novel, environmentally friendly procedure has been developed for the preparation of secondary or tertiary amines by one-pot reductive amination of carbonyl compounds using sodium borohydride in the presence of a magnetically recoverable sulfonic acid supported on hydroxyapatite-encapsulated-γ- Fe2O3 [γ-Fe2O3@HAP-SO 3H] at room temperature. The catalyst was easily separated from the reaction mixture by applying an external magnet and reused for six cycles without significant loss of catalytic activity.