110714-01-7

Basic information

• Product Name: (1S,2S,3R,4R)-1-Methoxy-3-((R)-3-trifluoromethyl-pyridine-2-sulfinyl)-7-oxa-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester
• CAS NO: 110714-01-7
• Molecular Weight: 501.567
• Mol File: 110714-01-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2S,3R,4R)-1-Methoxy-3-((R)-3-trifluoromethyl-pyridine-2-sulfinyl)-7-oxa-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S,3R,4R)-1-Methoxy-3-((R)-3-trifluoromethyl-pyridine-2-sulfinyl)-7-oxa-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester(110714-01-7)
• EPA Substance Registry System: (1S,2S,3R,4R)-1-Methoxy-3-((R)-3-trifluoromethyl-pyridine-2-sulfinyl)-7-oxa-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester(110714-01-7)

Safety Data

• Hazardous Substances Data: 110714-01-7(Hazardous Substances Data)

Upstream product

• 65018-52-2 1-menthyl propiolate 
• 104040-74-6 3-trifluoromethyl-2-mercaptopyridine 

Downstream Products

• 110694-73-0 (1S,2S,6R,7S,8R,9S)-7-Methoxy-4,4-dimethyl-9-((S)-3-trifluoromethyl-pyridine-2-sulfinyl)-3,5,10-trioxa-tricyclo[5.2.1.0^2,6]decane-8-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 110694-73-0 (1S,2R,6S,7S,8S,9R)-7-Methoxy-4,4-dimethyl-9-((S)-3-trifluoromethyl-pyridine-2-sulfinyl)-3,5,10-trioxa-tricyclo[5.2.1.0^2,6]decane-8-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 

Relevant articles and documents

ENANTIOSELECTIVE TOTAL SYNTHESIS OF GLYOXALASE I INHIBITOR USING ASYMMETRIC DIELS-ALDER REACTION OF A NEW CHIRAL DIENOPHILE, (S)S-3-(3-TRIFLUOROMETHYLPYRID-2-YLSULFINYL)ACRYLATE.

Highly enantioselective total synthesis of Glyoxalase I inhibitor (1) was achieved utilizing the assymetric Diels-Alder reaction of a new chiral dienophile, (S)S-menthyl 3-(3-trifluoromethylpyrid-2-ylsulfinyl)acrylate (3) with 2-methoxyfuran.