110715-69-0

Basic information

• Product Name: Cyclopropanemethanol, a-butyl-2-phenyl-
• CAS NO: 110715-69-0
• Molecular Formula: C14H20O
• Molecular Weight: 204.312
• Mol File: 110715-69-0.mol

Chemical Properties

• CAS DataBase Reference: Cyclopropanemethanol, a-butyl-2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanemethanol, a-butyl-2-phenyl-(110715-69-0)
• EPA Substance Registry System: Cyclopropanemethanol, a-butyl-2-phenyl-(110715-69-0)

Safety Data

• Hazardous Substances Data: 110715-69-0(Hazardous Substances Data)

Upstream product

• 593-71-5 Chloroiodomethane 
• 109801-00-5 (1E)-1-phenylhept-1-en-3-ol 
• 75-11-6 diiodomethane 

Downstream Products

• 110653-19-5 1-fluoro-1-phenyl-3-octene 

Relevant articles and documents

Samarium-Promoted Cyclopropanation of Allylic Alcohols

The use of samarium/mercury amalgam in conjunction with diiodomethane or chloroiodomethane to generate samarium carbenoids for the efficient cyclopropanation of allylic alcohols is discussed.These hydroxyl-directed cyclopropanations occur under mild conditions and allow a wide range of substitution about both the olefin and the carbinol carbon in allylic alcohol substrates.High yields and high diastereoselectivities are observed for many substrates.

Samarium-Promoted, Stereocontrolled Cyclopropanation Reactions

Samarium-based carbenoids have been found to be highly efficient cyclopropanation reagents for allylic alcohol substrates.Hydroxyl-directed cyclopropanations occur under very mild conditions with a high degree of selectivity.