1107595-15-2Relevant academic research and scientific papers
Heterocycles Derived from Generating Monovalent Pnictogens within NCN Pincers and Bidentate NC Chelates: Hypervalency versus Bell-Clappers versus Static Aromatics
Kremlá?ek, Vít,Hyvl, Jakub,Yoshida, Wesley Y.,Ruì??i?ka, Ale?,Rheingold, Arnold L.,Turek, Jan,Hughes, Russell P.,Dostál, Libor,Cain, Matthew F.
, p. 2481 - 2490 (2018)
Generating monovalent pnictogens within NCN pincers has resulted in the isolation of three distinct types of 1,2-azaheteroles, highly aromatic nitrogen analogues like pyrazole-based 5, aromatic yet fluxional P- and As-derived bell-clappers 1 and 2, and hy
Unexpected cyclization reaction of an overcrowded 2-phosphinophenylmethanimine derivative leading to the formation of the first stable 2-phospha-2h-isoindole derivative
Tokitoh, Norihiro,Matsumoto, Teruyuki,Sasamori, Takahiro
scheme or table, p. 981 - 987 (2009/06/28)
The reaction of overcrowded 2-phosphinophenylmethanimine derivative 1 bearing a 2,4,6-tri-t-butylphenyl (Mes*) group on the phosphorus atom and a 2,6-diisopropylphenyl (Dip) group on the nitrogen atom with potassium hydride afforded 2-phospha-2H-isoindole 2 along with Mes*H.
