1107604-19-2Relevant academic research and scientific papers
Experimental and theoretical investigations into the unusual regioselectivity of 4,5-, 5,6-, and 6,7-indole aryne cycloadditions
Garr, Ashley N.,Luo, Diheng,Brown, Neil,Cramer, Christopher J.,Buszek, Keith R.,Vandervelde, David
supporting information; experimental part, p. 96 - 99 (2010/03/04)
"Chemical Equation Presented" The 6,7-indolyne shows remarkable regioselectivity in its cycloaddition with 2-substituted furans. Electron-donating groups give predominantly the more sterically crowded product, while electron-withdrawing groups display the
Regioselective Diels-Alder cycloadditions and other reactions of 4,5-, 5,6-, and 6,7-indole arynes
Brown, Neil,Luo, Diheng,Vander Velde, David,Yang, Shaorong,Brassfield, Allen,Buszek, Keith R.
scheme or table, p. 63 - 65 (2009/04/14)
The regioselectivity of Diels-Alder cycloadditions of indole arynes (indolynes) at all three benzenoid positions was examined. Cycloadditions with the 4,5-and 5,6-indolynes, derived via metal-halogen exchange from the corresponding o-dibromo indoles, show
