1107604-48-7Relevant articles and documents
Microsphere vs. microbelt morphology of ionic palladium(II) complexes
Noh, Tae Hwan,Chun, In Sung,Lee, Young-A.,Ahn, Sungho,Hong, Jongki,Jung, Ok-Sang
, p. 1461 - 1464 (2008)
A series of palladium(II) complexes containing bis[(4-isonicotinoyloxy) phenyl]sulfide (L), [PdII(L)(tmen)]2X4(tmen =N,N,N'N'-tetramethylethane-1,2-diamine; X = NO 3 and CIO4) were prepared and characterized. Reaction of [Pd(tmen)](NO3)2 with L in a mixture of water and acetone affords microspheres whereas reaction of [Pd(tmen)](ClO4)2 with L produces microbelts. The solubility of the products is a significant factor for the formation of morphology. The spherical sizes can be controlled by the evaporation rate of solvents. An array of ≈300 nm and ≈ 4μ bimodal spheres was carried out via sonication.