1107605-99-1Relevant articles and documents
Electrogenerated chemiluminescence of benzo 15-crown-5 derivatives
Jiang, Xiao,Yang, Xichuan,Zhao, Changzhi,Sun, Licheng
, p. 1 - 8 (2009)
Novel electrogenerated chemiluminescence (ECL) reagents C1, C2, and C3 with high fluorescence quantum yields bearing 15-crown-5 moiety have been synthesized and characterized. The photophysical, electrochemical, and ECL characters of these compounds have been studied in a 1:1 (v/v) PhH/MeCN mixed solvent. The ECL intensity is enhanced distinctly with the increase in the fluorescence quantum yield. Their ECL behaviors have been studied using annihilation and co-reactant methods (tri-n-propylamine (TPrA) was used as a co-reactant), respectively. The stable ECL emissions of compounds C1-C3 can be ascribed to the typical and simple monomer ECL emission via S-route. Copyright