1107650-22-5Relevant academic research and scientific papers
Highly efficient and chemoselective α-iodination of acrylate esters through Morita-Baylis-Hillman-type chemistry
Pace, Vittorio,Vilkauskaite, Gyte,?a?kus, Algirdas,Holzer, Wolfgang
supporting information, p. 1085 - 1088 (2013/03/28)
The chemoselective α-iodination of various simple and multi-functionalised acrylic esters is efficiently accomplished by a Morita-Baylis-Hillman protocol involving the use of N-iodophthalimide, 3-quinuclidinol and KF-Celite in acetonitrile. No degradation of the obtained compounds was observed under the optimized conditions thus, furnishing α-iodoacrylates suitable for organometallic reactions (i.e. Nozaki-Kishi-Hiyama type coupling).
Exploring the reaction of iodine with α-diazo esters
Werardo, Giancarlo,Geatti, Paola,Gambi, Alberto
experimental part, p. 24 - 30 (2009/07/26)
In this paper we describe the unprecedented reaction between a-diazo esters 1 and iodine. The reaction, carried out in the presence of aqueous NaHCO 3, afforded the Z-isomer of the corresponding unsaturated-2-iodo ester 8, The configuration of
