1107651-84-2Relevant academic research and scientific papers
Hexa-: Peri-hexabenzocoronene decorated with an allenylidene ruthenium complex-Almost a flyswatter
Burzlaff, Nicolai,Jux, Norbert,Lorenz, Rebecca,Reger, David,Weller, Ruth
, p. 13134 - 13141 (2020)
Carbon-rich ruthenium allenylidene complexes bearing either a hexaarylbenzene (HAB) or a hexa-peri-hexabenzocoronene (HBC) substituent were synthesised. This was achieved via the corresponding propargyl alcohols with HAB and HBC substituents, which were accessible via 3 or 4 step reaction cascades. Reaction of the propargyl alcohols HCC(OH)Ph(HAB) and HCC(OH)Ph(HBC) with [RuCl(η5-C5H5)(PPh3)2] yielded the complexes [Ru(η5-C5H5)(CCC(HAB)(Ph))(PPh3)2]PF6 and [Ru(η5-C5H5)(CCC(HBC)(Ph))(PPh3)2]PF6. The latter of which shows interesting π-π-stacking behaviour in the solid state as well as aggregation in solution.
