110784-44-6

Basic information

• Product Name: 2,4-Cyclohexadien-1-one, 2,4,6-trimethyl-6-phenyl-
• CAS NO: 110784-44-6
• Molecular Formula: C15H16O
• Molecular Weight: 212.291
• Mol File: 110784-44-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,4-Cyclohexadien-1-one, 2,4,6-trimethyl-6-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Cyclohexadien-1-one, 2,4,6-trimethyl-6-phenyl-(110784-44-6)
• EPA Substance Registry System: 2,4-Cyclohexadien-1-one, 2,4,6-trimethyl-6-phenyl-(110784-44-6)

Safety Data

• Hazardous Substances Data: 110784-44-6(Hazardous Substances Data)

Upstream product

• 60-29-7 diethyl ether 
• 39150-80-6 Essigsaeure-(4-oxo-1,3,5-trimethylcyclohexa-2,5-dienyl)ester 
• 527-60-6 Mesitol 
• 3049-07-8 pentaphenylbismuth 
• 507233-69-4 triphenyl bismuth ⁽²⁺⁾; dichloride 

Relevant articles and documents

Oxidative dearomatization of phenols and anilines via λ3 - and λ5-iodane-mediated phenylation and oxygenation

Treatment of 2-methylphenols with chloro(diphenyl)-λ3- iodane led to their regioselective dearomatizing 2-phenylation into cyclohexa-2,4-dienone derivatives via a proposed ligand coupling reaction. In the same vein of investigation, treatment of 2-methylanilines with the λ5-iodane 2-iodoxybenzoic acid IBX reagent led to their regioselective dearomatization into previously undescribed ortho-quinol imines.

THE CHEMISTRY OF PENTAVALENT ORGANOBISMUTH REAGENTS. PART X. STUDIES ON THE PHENYLATION AND OXIDATION OF PHENOLS

The influence of the substituents on the phenol on the regiochemistry of the arylation reactions with Ph3BiCl2 and other bismuth reagents has been studied.O-Phenylation occurs with phenols substituted with electron-withdrawing groups.Electron-donating substituted phenols undergo ortho C-phenylation.Oxidative dimerisation has been observed with 2,6-dialkyl phenols.