110797-07-4Relevant academic research and scientific papers
Preparation of Medium-Ring Acetylenic Lactones Utilizing Metal-Promoted Alkyne Bending
Schore, Neil E.,Najdi, Samir D.
, p. 5296 - 5298 (2007/10/02)
Reaction of a variety of acetylenic hydroxycarbonyl compounds with Co2(CO)8 gives rise to readily isolated alkyne-Co2(CO)6 complexes in which lactonization, previously impossible due to geometric constraints, proceeds relatively smoothly due to "bending"
