110811-01-3Relevant academic research and scientific papers
1H-Azepin-3(2H)-ones
McNab, Hamish,Monahan, Lilian C.
, p. 141 - 142 (1987)
The reactivity of the title compounds (1) with acids, bases, and electrophiles, and in pericyclic processes is compared to the chemistry of the structurally related pyrrol-3-ones (2), pyridin-2-ones (3), and azepin-2-ones (4).
AZEPINONES. PART 3.1,2 REAKTIONS OF SIMPLE 1H-AZEPIN-3(2H)-ONES WITH ELECTROPHILES
McNab, Hamisch,Monahan, Lilian C.,Blake, Alexander J.
, p. 3163 - 3168 (2007/10/02)
The dienaminone conjugated system of 1H-azepin-3(2H)-ones (1) and (2) is active towards electrophiles at either oxygen or carbon centres.Analysis of 1H and 13C NMR spectra shows that O-protonation (trifluoroacetic acid) and O-alkylat
