110819-30-2Relevant academic research and scientific papers
REACTION OF SINGLET OXYGEN WITH METHYLENECYCLOPROPANES: FORMATION OF 4-METHYLENE-1,2-DIOXOLANES
Akasaka, Takeshi,Ando, Wataru
, p. 217 - 220 (2007/10/02)
Photosensitized oxygenation of adamantylidenecyclopropanes gave either the corresponding 4-methylene-1,2-dioxolane or lactone and cyclic ketone depending on the substituent on the cyclopropane ring.The results are rationalized in terms of initial formation of a perepoxide intermediate followed by that of an allylic cation-type zwitterion or a carbonyl oxide, respectively.
