110827-67-3

Basic information

• Product Name: indium(III)(5,10,15,20-tetraphenylporphyrin) azide
• CAS NO: 110827-67-3
• Molecular Weight: 769.573
• Mol File: 110827-67-3.mol

Chemical Properties

• CAS DataBase Reference: indium(III)(5,10,15,20-tetraphenylporphyrin) azide(CAS DataBase Reference)
• NIST Chemistry Reference: indium(III)(5,10,15,20-tetraphenylporphyrin) azide(110827-67-3)
• EPA Substance Registry System: indium(III)(5,10,15,20-tetraphenylporphyrin) azide(110827-67-3)

Safety Data

• Hazardous Substances Data: 110827-67-3(Hazardous Substances Data)

Upstream product

• 36522-28-8 (5,10,15,20-tetraphenylporphyrinato)(chloro)indium(III) 

Downstream Products

• 130669-39-5 (C₄₄H₂₈N₄)In{N₄C(CH₂CH₃)} 
• 143933-51-1 indium(III)(5,10,15,20-tetraphenylporphyrin){N₄C(CMe₃)} 
• 143933-52-2 In(C₂₀H₈N₄(C₆H₅)4){N₄C(CHCH₂)} 
• 143933-53-3 indium(III)(5,10,15,20-tetraphenylporphyrin){N₄C(CHCHCN)} 
• 110851-71-3 (C₄₄H₂₈N₄)In{N₄C(CH₃)} 
• 130669-40-8 (C₄₄H₂₈N₄)In{N₄C(NO₂C₆H₄)} 
• 130669-41-9 (C₄₄H₂₈N₄)In{N₃C₂(CO₂CH₃)2} 
• 110827-65-1 (4-phenyltetrazolato)(tetraphenylporphinato)indium(III) 

Relevant articles and documents

Metalloporphyrins containing σ-bonded nitrogen axial ligands. 1. Synthesis and characterization of indium(III) porphyrin complexes. Molecular structures of (4-phenyltetrazolato)- and (5-methyltetrazolato)(2,3,7,8,12,13,17,18-octaethylporphinato)indium(III)

The synthesis and characterization of 16 nitrogen σ-bonded (tetrazolato)- and (triazolato)indium(III) porphyrin complexes are reported. Each metalloporphyrin was characterized by UV-visible, IR, and 1H NMR spectroscopy as well as by electrochemistry. The molecular structure of (OEP)In[N4C(CH3)] was solved and compared to (OEP)In[N4C(C6H5)], whose characterization was reported in a preliminary communication. (OEP)In[N4C(CH3)] crystallizes in the triclinic system, space group P1 (a = 12.035 (2) A?, b = 12.855 (2) A?, c = 14.097 (3) A?, α = 110.00 (3)°, β = 111.10 (3)°, γ = 90.52 (3)°, Z = 2, ρ = 1.265 g cm-3, R(F) = 5.13%). The tetrazolato group of (OEP)In[N4C(CH3)] is substituted at the 5-position of the axial ligand, whereas the C6H5 group of (OEP)In[N4C(C6H5)] is substituted in the 4-position of the tetrazolato ligand. The spectroscopic data suggest that the tetrazole or triazole linkage mode depends upon the nature of the aryl or alkyl group attached to the axial ligand, and this was confirmed by structural data for two of the complexes.