110841-84-4Relevant articles and documents
Synthesis method of nickel-catalyzed C - 3 alkyl substituted quinoxalinone under electrochemical condition
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Paragraph 0006; 0059-0062, (2021/04/10)
The invention discloses a method for synthesizing C-3 alkyl substituted quinoxalinone by nickel catalysis under an electrochemical condition, and belongs to the technical field of preparation of compounds. The method comprises the steps: taking 2-hydroxyq
Nickel-catalyzed electrochemical reductive decarboxylative coupling of: N -hydroxyphthalimide esters with quinoxalinones
Lian, Fei,Xu, Kun,Meng, Wei,Zhang, Haonan,Tan, Zhoumei,Zeng, Chengchu
, p. 14685 - 14688 (2019/12/11)
Herein the first example of electrochemically enabled, NiCl2-catalyzed reductive decarboxylative coupling of N-hydroxyphthalimide (NHP) esters with quinoxalinones is reported. A range of primary, secondary, tertiary aliphatic carboxylic acids and amino acid-derived esters were tolerated well. This decarboxylative coupling allows access to structurally diverse 3-alkylated quinoxalinones in up to 91% yields.
Condensation of o-Phenylenediamines with Azlactones
Subhashini, N. J. Prameela,Hanumanthu, P.
, p. 32 - 35 (2007/10/02)
Condensation of o-phenylenediamines (I) with 4-arylidene-2-substituted-oxazolin-5-ones (II) (azlactones) in acetic acid results in the formation of 3-benzyl-2(1H)quinoxalinones (III) and substituted benzimidazoles (IV).Structures of these compounds have been established based on their spectral data, and direct comparison with authentic samples prepared by unambiguous routes.