110847-02-4

Basic information

• Product Name: (1R,3S)-2,2-DIMETHYL-3-(2-OXOPROPYL)-CYCLOPROPANEACETONITRILE
• Synonyms: (1R,3S)-2,2-DIMETHYL-3-(2-OXOPROPYL)-CYCLOPROPANEACETONITRILE;(1R,3S)-2,2-DIMETHYL-3-(2-OXOPROPYL)-CYCLOPROPANEACETONITRILE 99%;(1R,3S)-2,2-Dimethyl-3-(2-oxopropyl)-cyclopropaneacetonitrile,99%;2-[(1R,3S)-2,2-dimethyl-3-(2-oxopropyl)cyclopropyl]acetonitrile;2-[(1R,3S)-2,2-dimethyl-3-(2-oxopropyl)cyclopropyl]ethanenitrile;2-[(1R,3S)-3-acetonyl-2,2-dimethylcyclopropyl]acetonitrile;2-[(1R,3S)-3-acetonyl-2,2-dimethyl-cyclopropyl]acetonitrile
• CAS NO: 110847-02-4
• Molecular Formula: C10H15NO
• Molecular Weight: 165.23
• Mol File: 110847-02-4.mol

Chemical Properties

• Boiling Point: 132-133 °C (7 mmHg)
• Flash Point: 116.9°C
• Appearance: /
• Density: 0.96
• Vapor Pressure: 0.00716mmHg at 25°C
• Refractive Index: 1.458-1.46
• Storage Temp.: 0-6°C
• CAS DataBase Reference: (1R,3S)-2,2-DIMETHYL-3-(2-OXOPROPYL)-CYCLOPROPANEACETONITRILE(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,3S)-2,2-DIMETHYL-3-(2-OXOPROPYL)-CYCLOPROPANEACETONITRILE(110847-02-4)
• EPA Substance Registry System: (1R,3S)-2,2-DIMETHYL-3-(2-OXOPROPYL)-CYCLOPROPANEACETONITRILE(110847-02-4)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 24/25
• Hazardous Substances Data: 110847-02-4(Hazardous Substances Data)

Usage

Chemical Properties

Clear light amber oil

InChI:InChI=1/C10H15NO/c1-7(12)6-9-8(4-5-11)10(9,2)3/h8-9H,4,6H2,1-3H3/t8-,9+/m1/s1

Upstream product

• 72552-26-2 (+)-4β-Amino-3α-hydroxy-cis-carane 
• 131447-84-2 3-morpholinocaran-4-one oxime 

Downstream Products

• 14087-71-9 (-)-cis-dihydrochrysanthemolactone 
• 14087-70-8 (+)-Dihydrochrysanthemolactone 
• 141342-64-5 (1R,3S)-2,2-dimethyl-3-cyanocyclopropaneacetonitrile 
• 144686-83-9 (1R,3S)-2,2-dimethyl-3-<(2S)-2-(p-toluenesulfonyloxy)propyl>cyclopropaneacetonitrile 

Relevant articles and documents

Conversion of Cyclic Aziridines and 2-Amino-1-cycloalkanols to Keto Nitriles by Using Electrogenerated Reactive Halogen Species

Oxidative cleavage of C(1)-C(2) bond of aziridines and 2-amino-1-cycloalkanols, giving the corresponding keto nitriles, exclusively, have been performed by oxidation with electrogenerated reactive halogen species (e.g., +).

Conversion of Terpenic Compounds to ω-Ketonitriles

Conversion of unsaturated terpenoids with trisubstituted carbon-carbon double bond into α-aminooximes followed by treatment with phosphorus pentachloride results in the formation of seco-terpenic ω-ketonitriles.