110852-84-1Relevant academic research and scientific papers
Introduction of a Triple Bond into the Bicyclononane skeleton
Meier, Herbert,Antony-Mayer, Christina,Schulz-Popitz, Cornelius,Zerban, Georg
, p. 1087 - 1094 (2007/10/02)
The introduction of a triple bond into the bicyclononane skeleton is investigated by applying the selenadiazole method to ketones 1a-c, accessible on different pathways.The highly strained bicyclononynes 2a and 2b can be isolated in pure state.The regioselectivity of the ring-closure reaction yielding the selenadiazoles determines the position of the triple bond.
