110897-39-7

Upstream product

• 17530-69-7 3-chloro-5,5-dimethylcyclohex-2-en-1-one 
• 131534-66-2 diisopropyl [(Z)-(2-hepten-2-yl)]boronate 
• 91083-32-8 <(Z)1-Bromo-1-hexenyl>diisopropoxyborane 
• 917-54-4 methyllithium 

Relevant academic research and scientific papers

Stereoselective Synthesis of Conjugated Dienones via the Palladium-Catalyzed Cross-Coupling Reaction of 1-Alkenylboronates with 3-Halo-2-alken-1-ones

The synthesis of conjugated dienones by means of palladium-catalyzed cross-coupling reaction between (E)-1-alkenyl-1,3,2-benzodioxaboroles or diisopropyl (Z)-1-hexenylboronate with 3-halo-2-alken-1-ones is described.

Stereo- and Regiospecific Synthesis of Trisubstituted Alkenes via the Palladium-catalyzed Cross-coupling Reaction of Diisopropyl (E)-(1-Alkyl-1-alkenyl)boronates with Organic Halides

The reaction of diisopropyl (Z)-(1-bromo-1-alkenyl)boronates readily obtainable, with organolithiums and bases takes place readily to give (E)-(1-organo-1-alkenyl)boronates, the cross-coupling of which with various organic halides proceeds smoothly in the presence of Pd-catalyst and base to afford stereodefinied trisubstituted alkenes in good yields.