110960-77-5Relevant articles and documents
Sulfur-carbon bond formation through ring-opening of triazolothiadiazole with organometallics
Othman, Raja Ben,Massip, Stephane,Marchivie, Mathieu,Jarry, Christian,Vercouillie, Johnny,Chalon, Sylvie,Guillaumet, Gerald,Suzenet, Franck,Routier, Sylvain
, p. 3225 - 3231 (2014/06/09)
An efficient and convenient method was developed for the formation of S-substituted thiotriazoles through an unprecedented organometallic addition and subsequent ring-opening sequence of 3-substituted [1,2,4]triazolo[3,4-b][1,3,4] thiadiazole. The method is applicable to a wide range of substrates containing different functional groups and furnishes excellent yields of the corresponding N-unsubstituted 3- or 5-alkyl, aryl, alkynyl and alkenyl sulfanyl-1,2,4-triazole products. Copyright