110995-45-4Relevant academic research and scientific papers
Structure, Synthesis and Absolute Configuration of Leptosphaerin, a Metabolite of the Marine Ascomycete Leptosphaeria oraemaris.
White, James D.,Badger, Rodney A.,Kezar III, Hollis S.,Pallenberg, Alexander J.,Schiehser, Guy A.
, p. 6631 - 6644 (2007/10/02)
A structure 3 erroneously deduced for the marine fungal metabolite leptosphaerin on the basis of spectroscopic evidence and an ambiguous x-ray analysis was disproved by synthesis.An alternative formulation 1, including its absolute configuration, was conf
THE SYNTHESIS AND ABSOLUTE CONFIGURATION OF (+)-LEPTOSPHAERIN
Pallenberg, Alexander J.,White, James D.
, p. 5591 - 5594 (2007/10/02)
A synthesis of (+)-leptosphaerin (1), a metabolite of the marine ascomycete Leptosphaeria oraemaris (Linder), was accomplished from (R)-glyceraldehyde by a route that confirms the structural assignment and establishes the absolute configuration of 1 as (4S,5R).
