111018-05-4Relevant academic research and scientific papers
Cationic Ruthenium(II) Phosphite Complexes. Preparation and Properties of Monocarbonyl and Isocyanide Derivatives
Albertin, Gabriele,Antoniutti, Stefano,Bordignon, Emilio
, p. 1813 - 1816 (1987)
Mono- and tri-μ-chloro ruthenium(II) complexes BPh4 and BPh4 were prepared by alowing ruthenium trichloride to react with phosphite in refluxing ethanol.Cationic carbonyl derivatives of the type trans-+ were also prepared by the carbonylation reaction of a phosphite-containing RuCl3 solution.The raection of all these compounds with isocyanide was examined and led to the synthesis of the new +, 2+, and + derivatives.Characterization of the complexes by i.r. and 1H and 31P n.m.r. data is also discussed.
