111021-09-1

Basic information

• Product Name: 1-phenylethyl 2-chlorobenzoate
• Synonyms: 1-phenylethyl 2-chlorobenzoate
• CAS NO: 111021-09-1
• Molecular Weight: 260.72
• Mol File: 111021-09-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-phenylethyl 2-chlorobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylethyl 2-chlorobenzoate(111021-09-1)
• EPA Substance Registry System: 1-phenylethyl 2-chlorobenzoate(111021-09-1)

Safety Data

• Hazardous Substances Data: 111021-09-1(Hazardous Substances Data)

Upstream product

• 100-41-4 ethylbenzene 
• 118-91-2 ortho-chlorobenzoic acid 

Relevant articles and documents

A metal-free oxidative esterification of the benzyl C-H bond

An efficient metal-free oxidative esterification of benzyl C-H bonds was developed. Using tetrabutylammonium iodide as catalyst and tert-butyl hydroperoxide as co-oxidant, benzylic substrates could react smoothly with various carboxylic acids to give the esters with good to excellent yields. The method was also suitable for the O-protection of N-Boc amino acids. The reaction mechanism was primarily investigated and a radical process was proposed. Copyright