111026-17-6

Basic information

• Product Name: {(iron(carbonyl)(nitrosyl)2)2(μ-dppm)}
• CAS NO: 111026-17-6
• Molecular Weight: 672.136
• Mol File: 111026-17-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: {(iron(carbonyl)(nitrosyl)2)2(μ-dppm)}(CAS DataBase Reference)
• NIST Chemistry Reference: {(iron(carbonyl)(nitrosyl)2)2(μ-dppm)}(111026-17-6)
• EPA Substance Registry System: {(iron(carbonyl)(nitrosyl)2)2(μ-dppm)}(111026-17-6)

Safety Data

• Hazardous Substances Data: 111026-17-6(Hazardous Substances Data)

Upstream product

• 64345-29-5 [Pd2Cl2(μ-bis(diphenylphosphino)methane)2] 
• 25875-19-8 K{iron(carbonyl)3nitrosyl} 
• 2071-20-7 bis-diphenylphosphinomethane 

Relevant articles and documents

The synthesis and structural characterization of linear and macrocyclic bis(dinitrosyliron) complexes supported by bis(phosphine) bridging ligands

Reactions involving Fe(NO)2(CO)2 and the bis(phosphine) ligands bis(diphenylphosphino)methane (DPPM), bis(diphenylphosphino)acetylene (DPPA), 1,6-bis(diphenylphosphino)hexane (DPPH), and 1,4-bis(diphenylphosphino)-benzene (DPPB) have been examined. From these reactions, the mononuclear complex, Fe(κ1-DPPM)(NO) 2(CO) 3, linear dinuclear species of the type Fe2(μ -L)(NO)4(CO)2 (L = Ph2PCH2PPh 2 4, Ph2PC≡CPPh2 5, Ph 2PCH2(CH3)4CH2PPh 2 6, and Ph2P(p-C6H4)PPh 2 7), and macrocyclic dinuclear species of the type Fe 2(μ-L)2(NO)4 (L = Ph2PCH 2PPh2 8 and Ph2PC≡CPPh2 9) were isolated and spectroscopically characterized. For 4, 5, 8, and 9, the solid-state molecular structures of the products were determined by use of single-crystal X-ray diffraction techniques.