Silicomolybdic acid that is supported on silica gel (50 wt %) efficiently catalyzes the high-yielding Hosomi–Sakurai allylation of carbonyl compounds by allyltrimethylsilane in the presence of benzyl alcohol. The reaction rates of inactive substrates and the yields were greatly increased when p...detailed
Beta silicomolibdic acid/silica (β-SMA, a metastable form of silicomolybdic acid – H4SiMo12O40) forms by the impregnation of fumed silica into molybdenum solution obtained by hydrolyzation of MoO2Cl2. β-SMA/silica is found to be stable up to 300 °C after calcination for 1 h due to the existe...detailed
In this paper, we report our investigation into the immobilization of silicomolybdic acid on hollow mesoporous silica spheres and the activity of the modified spheres for hydrolytic dehydrogenation of ammonia borane. Silica shells were coated onto polystyrene (PS) template particles by the sol–...detailed