111076-06-3Relevant academic research and scientific papers
Convenient synthesis and cycloaddition reactions of 2-phenylseleno-1,3-butadiene and 2-trialkylstannyl-1,3-butadienes
Bates, Gordon S.,Fryzuk, Michael D.,Stone, Charles
, p. 2612 - 2617 (2007/10/02)
The facile preparation of 2-trialkylstannyl-1,3-butadienes and 2-phenylseleno-1,3-butadiene by reaction of 2-(1,3-butadienyl)magnesium chloride with trialkylstannyl chlorides and phenylselenium chloride, respectively, is reported.The Diels-Alder reactivity of these dienes with a variety of activated dienophiles is also described.Finally, a novel transmetallation of tin, in vinyl stannanes, to selenium by use of phenylselenium chloride is outlined.
