111143-60-3Relevant academic research and scientific papers
SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY OF A Pd(II) COMPLEX OF BIS(2-(DIPHENYLPHOSPHINO)ETHYL) - BENZYLAMINE IN THE HOMOGENEOUS HYDROGENATION OF CYCLOHEXENE.
Reddy V.Vijay Sen
, p. 73 - 84 (2008/10/08)
The synthesis and characterization of left bracket PdCl(DPBA) right bracket Cl 1 (DPBA equals bis(2-(diphenylphosphino)ethyl)benzylamine) has been carried out. The catalytic activity of 1 in the homogeneous hydrogenation of cyclohexene over the temperature range 25-40 degree C and 0. 1-1 atm H//2 partial pressure has been investigated. The dependence of the rate of hydrogenation on factors such as the catalyst concentration, the substrate concentration, H//2 pressure and the temperature is reported. Two mechanisms have been proposed in which the catalyst 1 activates molecular hydrogen by forming hydrido species which are characterized by proton and **3**1P left brace **1H right brace NMR spectra.
