111172-74-8Relevant academic research and scientific papers
Attempted Synthesis of Osmium(VI) and Iridium(VI) Thiofluorides; the Preparation of OsF5.SF4 and IrF5.SF4
Holloway, John. H,Rook, John
, p. 2285 - 2288 (2007/10/02)
The interaction of OsF4 or IrF4 with ZnS or B2S3 at elevated temperature yields the adducts OsF5.SF4 and IrF5.SF4 rather than the trasition-metal thiofluorides.Infrared and X-ray powder diffraction studies indicate that the adducts have contributions to the bonding from the ionic formulations +- and +- and there is also (19)F n.m.r. evidence for the latter in solution in anhydrous HF.
