111180-54-2Relevant academic research and scientific papers
Reactions of polyfluoroaromatic compounds with electrophilic agents. Part 20. Nitrofluorination of pentafluorophenoxydifluoromethane and decafluorodiphenyl ether
Shtark, A. A.,Shteingarts, V. D.
, p. 93 - 100 (2007/10/02)
When nitrofluorinated with HNO3 in anhydrous HF, the pentafluorophenol ethers C6F5OR (R=CHF2, C6F5) add the nitronium cation to the para and ortho positions with respect to the substituent or eventually to form the corresponding 3-nitrocyclohexa-1,4-diene
REACTION OF POLYFLUORINATED DERIVATIVES OF BENZENE CONTAINING HYDROGEN ATOMS IN THE SIDE CHAIN WITH VANADIUM PENTAFLUORIDE
Avramenko, A. A.,Bardin, V. V.,Karelin, A. I.,Krasil'nikov, V. A.,Tushin, P. P.,et al.
, p. 2318 - 2323 (2007/10/02)
The treatment of C6F5R (R=CH3, CH2F, CHF2) compounds with vanadium pentafluoride at -25 to -30 deg C leads to a 1-R-heptafluoro-1,4-cyclohexadienes, 1-R-nonafluorocyclohexenes, and products form fluorination of the side chain.Fluorination of the anisole derivatives C6F5OCH3 and C6F5OCHF2 only takes place in the aromatic ring.
