111183-89-2

Upstream product

• 19715-27-6 Bis-(2,4,6-tri-tert.-butyl-phenyl)-disulfid 

Downstream Products

• 119872-27-4 N-Phenyl-S-(2,4,6-tri-tert-butyl-phenyl)-thiohydroxylamine 
• 119872-36-5 C₂₇H₃₈NO₂S 
• 119872-35-4 C₂₅H₃₆NOS 
• 119872-38-7 C₂₄H₃₃BrNS 
• 119872-37-6 C₂₄H₃₃ClNS 
• 119872-34-3 C₂₅H₃₆NS 
• 119872-33-2 C₂₄H₃₄NS 
• 119872-30-9 4-(2,4,6-Tri-tert-butyl-phenylsulfanylamino)-benzoic acid ethyl ester 
• 111183-93-8 Bis(2,4,6-tri-tert-butylphenylsulfenyl)schwefeldiimid 
• 111183-94-9 2,4,6-Tri-tert-butylbenzensulfensaeureamid 
• 19715-27-6 Bis-(2,4,6-tri-tert.-butyl-phenyl)-disulfid 
• 111183-91-6 Bis(2,4,6-tri-tert-butylphenylthio)aminyl-radical 
• 119872-29-6 N-(4-Methoxy-phenyl)-S-(2,4,6-tri-tert-butyl-phenyl)-thiohydroxylamine 
• 119872-31-0 N-(4-Chloro-phenyl)-S-(2,4,6-tri-tert-butyl-phenyl)-thiohydroxylamine 

Relevant academic research and scientific papers

Trapping of in situ Prepared Arylsulfenyl Isocyanates with Alcohols and Amines. Preparation of Arylsulfenylcarbamates and Arylsulfenylureas

Arylsulfenyl isocyanates, which were in situ prepared from arylsulfenyl chlorides and silver (or sodium) cyanate, reacted with alcohols and primary amines at carbon of the isocyanato group to afford the corresponding arylsulfenylcarbamates and arylsulfenylureas, respectively.

Attempts to Synthesize Sterically Hindered Thiazyl Arenes and Their Relationship to Arylsulfenyl Nitrenes

Up till now all attempts to synthesize organic thiazyl compounds in substance failed.Stabilization leads to the corresponding disulfide 2, the thioaminyl radical 7 and the sulphur diimide 8.Formally thiazyl compounds 1 and sulfenyl nitrenes 1 were resonance structures.Via sulfenyl nitrenes 1 the formation of 2, 7, 8 can be discussed.An in situ preparation of sulfenyl nitrene 1a via the sulfenyl chloride 5a, synthesized by chlorination of the disulfide 2a, and the sulfenyl azide 6a is described in detail. 1a can also be prepared from the sulfenyl amide 4a by oxidation.The structures of the radicals 7a-f and 12f are discussed.