111195-52-9Relevant academic research and scientific papers
CROSS COUPLING OF 1,1,ω-TRICHLORO-1-ALKENES WITH ALKYLMAGNESIUM CHLORIDES WITH CATALYSIS BY PALLADIUM(II) AND COPPER(II) COMPLEXES AND SYNTHESIS OF 10-PROPYL-5(E),9-TRIDECADIEN-1-YL ACETATE ("PROPYLURE")
Zakharkin, L. I.,Anikina, E. V.
, p. 2217 - 2221 (2007/10/02)
The cross coupling of 1,1,ω-trichloro-1-alkenes with RMgCl (R=CH3, C3H7, C4H9) was realized with (Ph3P)2PdCl2 and Li2CuCl4 as catalysts.The two vinylic chlorine atoms are substituted by the alkyl groups without affecting the chlorine atom in the chloromet
