111196-93-1

Basic information

• Product Name: (+/-)-(1R,4R,5R,6R)-5,6-exo-epoxy-7-oxabicyclo<2.2.1>heptan-2-one
• CAS NO: 111196-93-1
• Molecular Weight: 126.112
• Mol File: 111196-93-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (+/-)-(1R,4R,5R,6R)-5,6-exo-epoxy-7-oxabicyclo<2.2.1>heptan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(1R,4R,5R,6R)-5,6-exo-epoxy-7-oxabicyclo<2.2.1>heptan-2-one(111196-93-1)
• EPA Substance Registry System: (+/-)-(1R,4R,5R,6R)-5,6-exo-epoxy-7-oxabicyclo<2.2.1>heptan-2-one(111196-93-1)

Safety Data

• Hazardous Substances Data: 111196-93-1(Hazardous Substances Data)

Upstream product

• 79902-01-5 2-endo-acetoxy-7-oxabicyclo<2.2.1>hept-5-ene-2-exo-carbonitrile 
• 111196-94-2 (1RS,2SR,4RS,5RS,6RS)-2-exo-cyano-5,6-exo-epoxy-7-oxabicyclo<2.2.1>hept-2-endo-yl acetate 

Downstream Products

• 120104-67-8 (+/-)-(1S,2S,4R,5R,6S)-5,6-exo-epoxy-7-oxabicyclo<2.2.1>heptan-2-exo-ol 
• 120104-67-8 (+/-)-(1S,2R,4R,5R,6S)-5,6-exo-epoxy-7-oxabicyclo<2.2.1>heptan-2-endo-ol 

Relevant articles and documents

FACILE MIGRATION OF ACYL GROUPS IN WAGNER-MEERWEIN TRANSPOSITIONS. ACID-CATALYZED REARRANGEMENTS OF 5,6-exo-EPOXY-7-OXA-2-BICYCLOHEPTANONE AND DERIVATIVES.

The acid promoted rearrangements of 5,6-exo-epoxy-7-oxa-2-norbornyl derivatives allowed one to compare the "true" migratory aptitudes of acyl, alkyl and α-substituted alkyl groups in Wagner-Meerwein rearrangements.