111198-29-9Relevant academic research and scientific papers
Azoles. Part 43:1 reactions of N-(phenylsulphonylmethyl)- and N-(phenylsulphinylmethyl)azoles with some nitroarenes
Bernard, Marek K
, p. 7273 - 7284 (2007/10/03)
Treatment of nitroarenes with 1-(phenylsulphonylmethyl)azoles in the KOH/DMSO system at room temperature resulted usually in the cleavage of the phenylsulphonyl group, whereas the t-BuOK/DMF system at low temperature promotes to a greater extent oxidation of the σ-adducts. When 1-(phenylsulphinylmethyl)azoles were used for the reaction only elimination of the phenylsulphinyl group was observed. (C) 2000 Elsevier Science Ltd.
The Lithiation of 1-(Phenylthiomethyl)benzimidazole and Related Compounds.
Katritzky, Alan R.,Ramer, Wolfgang H.,Lam, Jamshed N.
, p. 775 - 780 (2007/10/02)
1-(Phenylthiomethyl)benzimidazole is lithiated initially at the 2-position and at low temperatures the 2-lithio derivative reacts with active electrophiles to form 2-substituted products.At higher temperatures rearrangement occurs to a rather unstable met
