1112-94-3Relevant articles and documents
Preparation of (Dialkoxyphosphinyl)-methyl-Substituted Ketene Alkyl Trimethylsilyl Acetal Derivatives
Okamoto, Yoshiki,Sakurai, Hiroshi
, p. 497 - 499 (1982)
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Comparison of catalytic activity of hexamethyltriamino- and tri-n-butylphosphines in the Pudovik reaction
Salin, Alexey V.,Il’in, Anton V.
, p. 355 - 356 (2019/01/04)
The catalytic activity of hexamethyltriaminophosphine in the P(O)–H bond addition to electron-deficient alkenes was studied. Depending on the nature of the alkene, hexamethyltriaminophosphine produces better or lower yields of the reaction products compared to tri-n-butylphosphine.
Generation of the Methoxycarbonyl Radical by Visible-Light Photoredox Catalysis and Its Conjugate Addition with Electron-Deficient Olefins
Slutskyy, Yuriy,Overman, Larry E.
supporting information, p. 2564 - 2567 (2016/07/06)
Visible-light photoredox-catalyzed fragmentation of methyl N-phthalimidoyl oxalate allows the direct construction of a 1,4-dicarbonyl structural motif by a conjugate addition of the methoxycarbonyl radical to reactive Michael acceptors. The regioselectivity of the addition of this alkoxyacyl radical species to electron-deficient olefins is heavily influenced by the electronic nature of the acceptor, behavior similar to that exhibited by nucleophilic alkyl radicals.
One-pot synthesis of γ-hydroxy-γ-oxaphosphonates using pentacovalent oxaphosphorane chemistry
Hwang, Jae-Min,Islam, Tasneem,Jung, Kang-Yeoun
experimental part, p. 6076 - 6078 (2010/03/03)
P(V)-2,2,2-triethoxy-2,2-dihydro-5-methoxy-1,2λ5-oxaphospholene was synthesized as a new type of enolate which was hydrolyzed to give a series of phosphonates. In addition, aldol reaction of the oxaphospholene intermediate with several aldehyde
