1112264-96-6Relevant articles and documents
[bmim][OTf]: a versatile room temperature glycosylation promoter
Galan, M. Carmen,Brunet, Claire,Fuensanta, Monica
, p. 442 - 445 (2009)
[bmim][OTf] is a versatile, ionic liquid promoter for the room temperature glycosylation of both thiophenyl and trichloroacetimidate glycoside donors; the conditions are mild, with no requirement for molecular sieves, and are compatible with a wide range
N-benzoylglycine/thiourea cooperative catalyzed stereoselective O-glycosidation: Activation of O-glycosyl trichloroacetimidate donors
Dubey, Atul,Sangwan, Rekha,Mandal, Pintu Kumar
, p. 123 - 129 (2019/04/17)
A new practical utility for β-stereoselective glycosylation via activation of O-glycosyl trichloroacetimidate donors using N-benzoylglycine/thiourea cooperative catalysis has been demonstrated. This method represents the first instance where amino acid derived N-benzoylglycine is used as a catalyst for O–glycosylation under mild reaction conditions at ambient temperature. NMR spectroscopy studies suggest that thiourea cocatalyst exhibit a cooperative behaviour that has a strong effect on the reaction rate, yield, and the β-selectivity.