1112840-19-3Relevant academic research and scientific papers
GlucoSiFA and LactoSiFA: New Types of Carbohydrate-Tagged Silicon-Based Fluoride Acceptors for 18F-Positron Emission Tomography (PET)
Wiegand, Anja,Wiese, Vera,Glowacki, Britta,Iovkova, Ljuba,Schirrmacher, Ralf,Jurkschat, Klaus,Krause, Norbert
, p. 1196 - 1206 (2019)
GlucoSiFA derivatives bearing an azide or alkynyl side chain were obtained from peracetyl- d -glucose using as key step a tosylate substitution by a SiFA thiolate obtained from 4-(di- tert -butylfluorsilyl)benzenethiol. In analogy, two-fold SiFA-substituted maltose and lactose derivatives were synthesized via bistosylates. Introduction of an acetal-protecting group in β- d -azidolactose allowed the synthesis of a LactoSiFA derivative bearing only one SiFA moiety.
Para-functionalized aryl-di-tert-butylfluorosilanes as potential labeling synthons for18F radiopharmaceuticals
Iovkova, Ljuba,Waengler, Bjoern,Schirrmacher, Esther,Schirrmacher, Ralf,Quandt, Gabriele,Boening, Guido,Schuermann, Markus,Jurkschat, Klaus
experimental part, p. 2140 - 2147 (2009/10/01)
The syntheses of the functionalized triorganofluorosilanes tBu 2-(P-XC6H4)SiF (3 a, X = SH; 4 a, X = NCS; 4b, X = NCO; 5, X = NC4H2O2; 7, X = COOH; 8 a, X = COONC4H4O
