1112844-63-9

Upstream product

• 1112844-62-8 (4S,4'R,5R)-5-(5-(benzyloxy)pentyl)-2,2,2',2'-tetramethyl-4,4'-bi(1,3-dioxolane) 
• 1422039-43-7 (4S,4'R,5R)-5-((Z)-5-(benzyloxy)pent-1-enyl)-2,2,2',2'-tetramethyl-4,4'-bi(1,3-dioxolane) 
• 13039-93-5 2,2:4,5-di-O-isopropylidene-D-arabinose 
• 38145-93-6 1,2:3,4-di-O-isopropylidene-D-mannitol 

Downstream Products

• 1112844-65-1 (R)-2-((4R,5R)-5-(5-(benzyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-hydroxyethyl 4-methyl-benzenesulfonate 
• 1422039-51-7 (6R,7S,8R)-1-(benzyloxy)tetradec-10-yne-6,7,8-triol 
• 1422039-52-8 (6R,7S,8R)-1-(benzyloxy)-6,7-dihydroxyhexadec-10-yn-8-yl benzoate 
• 1422039-45-9 (R)-2-((4S,5R)-5-(5-(benzyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-(methylsulfonyloxy)ethyl benzoate 
• 1422039-46-0 (4R,5S)-4-(5-(benzyloxy)pentyl)-2,2-dimethyl-5-((S)-oxiran-2-yl)-1,3-dioxolane 
• 1422039-48-2 (R)-1-((4R,5R)-5-(5-(benzyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl)non-3-yn-1-ol 
• 1422039-50-6 (S)-1-((4S,5R)-5-(5-(benzyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl)non-3-ynyl benzoate 
• 1422039-53-9 (6R,7S,8S)-1-(benzyloxy)tetradec-10-yne-6,7,8-triol 
• 1422039-54-0 (6R,7S,8S)-1-(benzyloxy)-6,7-dihydroxyhexadec-10-yn-8-yl benzoate 
• 1422039-55-1 (1R,2R,5S,7R)-7-(5-(benzyloxy)pentyl)-5-pentyl-6,8-dioxabicyclo[3.2.1]octan-2-ol 
• 1422039-56-2 (1R,2R,5S,7R)-7-(5-(benzyloxy)pentyl)-5-pentyl-6,8-dioxabicyclo[3.2.1]octan-2-ol 
• 1422039-57-3 (1R,2R,5S,7R)-7-(5-(benzyloxy)pentyl)-5-pentyl-6,8-dioxabicyclo[3.2.1]octan-2-ol 
• 1422039-58-4 (1S,2S,5S,7R)-7-(5-(benzyloxy)pentyl)-5-pentyl-6,8-dioxabicyclo[3.2.1]octan-2-yl benzoate 
• 1112844-72-0 (R)-1-((4R,5R)-5-(5-(benzyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-19-(tert-butyldimethylsilyloxy)nonadec-3-yn-1-ol 

Relevant academic research and scientific papers

Metal-mediated alkynediol cycloisomerization: First and second generation formal total syntheses of didemniserinolipid B

A formal total synthesis of didemniserinolipid B was developed by employing a regioselective metal-mediated 6-endo-dig alkynol-cycloisomerization reaction. Two routes for the synthesis of key Burke's intermediate have been developed. Our initial approach

A formal synthesis of (+)-didemniserinolipid B employing a Pd-mediated 6-endo selective alkynediol cycloisomerization

Herein, we describe a concise assembly of central 6,8-dioxabicyclo[3,2,1]octane core of didemniserinolipid by employing a Pd-mediated alkynediol cycloisomerization and a formal total synthesis of didemniserinolipid B.