1112955-45-9Relevant academic research and scientific papers
A novel protecting group methodology for syntheses using nitroxides
Chalmers, Benjamin A.,Morris, Jason C.,Fairfull-Smith, Kathryn E.,Grainger, Richard S.,Bottle, Steven E.
supporting information, p. 10382 - 10384 (2013/10/22)
The methoxyamine group represents an ideal protecting group for the nitroxide moiety. It can be easily and selectively introduced in high yield (typically >90%) to a range of functionalised nitroxides using FeSO 4·7H2O and H2O2 in DMSO. Its removal is readily achieved under mild conditions in high yield (70-90%) using mCPBA in a Cope-type elimination process.
The synthesis and physical properties of novel polyaromatic profluorescent isoindoline nitroxide probes
Fairfull-Smith, Kathryn E.,Bottle, Steven E.
experimental part, p. 5391 - 5400 (2009/05/07)
New profluorescent mono- and di-isoindoline nitroxides (5, 11, 16 and 19) containing 9,10-diphenylanthracene and 9,10-bis(phenylethynyl)anthracene structural cores were synthesised by palladium-catalysed Suzuki and Sonogashira couplings. These nitroxide-f
