111323-52-5

Basic information

• Product Name: C₁₅H₁₃ClF₃NO₃S
• Synonyms: C₁₅H₁₃ClF₃NO₃S
• CAS NO: 111323-52-5
• Molecular Weight: 379.787
• Mol File: 111323-52-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₁₃ClF₃NO₃S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₁₃ClF₃NO₃S(111323-52-5)
• EPA Substance Registry System: C₁₅H₁₃ClF₃NO₃S(111323-52-5)

Safety Data

• Hazardous Substances Data: 111323-52-5(Hazardous Substances Data)

Upstream product

• 35673-10-0 bis(3-(trifluoromethyl)benzenesulfonyl) peroxide 
• 104-11-0 N-methyl-4-chlorobenzylamine 

Downstream Products

• 13114-22-2 N-(4-chlorobenzylidene)methylamine 

Relevant articles and documents

Reactions of N-(Arylsulfonoxy)-N-benzylmethylamines with Sodium Methoxide in Methanol

Reactions of N-(arylsulfonoxy)-N-benzylmethylamines (1) with MeONa in MeOH have been investigated.The eliminations are quantitative, producing only benzylidenemethylamines.The reactions are first order in substrate and first order in base, and an E2 mechanism is evident.Comparison of the rate data reveals that the arenesulfonates are better leaving groups than halogens in imine-forming elimination.For elimination from 1, ρ = 1.14, kH?kD = 3.6, ρlg = 1.30, and β1g = -0.43 have been calculated.Differences in the transition-sate characters for imine-forming eliminations from ArCH2N(Cl)CH3 and 1 have been intepreted in terms of changes in the leaving-group properties and base strength.