111400-53-4Relevant academic research and scientific papers
THERMAL REARRANGEMENT OF 3H-PYRROLES BY COMPETITIVE -SIGMATROPIC SHIFTS, AND THE REVERSIBILITY OF THE 3H- TO 2H-PYRROLE INTERCONVERSION
Chiu, Pak-Kan,Sammes, Michael P.
, p. 2775 - 2778 (2007/10/02)
3-Ethoxycarbonyl-3H-pyrroles are converted via thermal -ester shifts to the isomeric 1H-pyrrole-4- and N-esters.Isolable intermediate 2H-pyrroles are converted into the same products, and also into the 3H-pyroles, demonstrating conclusively the reversibility of the 3H- to 2H-pyrrole interconversion.
