111437-08-2Relevant articles and documents
A supramolecular ensemble of a PBI derivative and Cu2O NPs: Potential photocatalysts for the Suzuki and Suzuki type coupling reactions
Singh, Gurpreet,Kumar, Manoj,Sharma, Kamaldeep,Bhalla, Vandana
, p. 3278 - 3285 (2016)
The aggregates of the PBI derivative 1 in combination with Benedict's reagent have been used for the first time as reactors for facile preparation of Cu2O NPs at room temperature. During this process the aldehyde groups of the aggregates of derivative 1 are oxidized to carboxylate groups which act as stabilizers for Cu2O NPs to generate the supramolecular ensemble 2:Cu2O. Interestingly, the in situ generated supramolecular ensemble (2:Cu2O) of Cu2O NPs and aggregates of oxidized species 2 exhibited excellent photocatalytic efficiency in the Suzuki-Miyaura and Suzuki type cross-coupling reactions under mild and eco-friendly conditions.
Phenethylamino sulfamic acids
-
Page 31, (2010/02/08)
Compounds of formula (I): are effective in the treatment of protein tyrosine phosphatase (PTPase) mediated disorders such as diabetes.
Molecular Armatures. Synthesis and Structure of Troegers Base Analogues Derived from 4-, 2,4-, 3,4-, and 2,4,5-Substituted Aniline Derivatives
Sucholeiki, Irving,Lynch, Vincent,Phan, Ly,Wilcox, Craig S.
, p. 98 - 104 (2007/10/02)
The preparation of biomimetic systems designed to mimic natural receptor sites and enzymic active sites requires the development of new synthetic strategies for preparing large molecules with predictable and well-defined shapes.In this paper a number of derivatives of 6H,12H-5,11-methanodibenzodiazocines are prepared.The scope and limitations of the reaction of formaldehyde with aniline derivatives are examined.The molecules prepared have potential value as conformationally restricted armatures for the construction of biomimetic molecular systems.A crystallographic study reveals that the molecules are folded and that the angle formed by the two aryl rings ranges from 88 deg to 104 deg.Sulfonamides, bromides, alcohols, and amines can be introduced as side-chain substituents in these systems.