1114435-46-9Relevant academic research and scientific papers
Allenylzincs and tert-butylsulfinylimines: A fruitful marriage for synthesis
Botuha, Candice,Chemla, Fabrice,Ferreira, Franck,Louvel, Julien,Perez-Luna, Alejandro
, p. 1147 - 1153 (2010)
The stereoselective synthesis of alkynyl 1,2-amino alcohols by the addition of 3-chloro-and 3-methoxymethoxy-allenylzincs to chiral tert- butylsulfinylimines is described. The methodology is applicable to the preparation of alkynyl 2-amino-1,3-diols (O,N,O stereotriads) using α-alkoxy tert-butylsulfinylimines as chiral starting materials. The scope and limitations of the methodology along with recent applications to the efficient asymmetric syntheses of natural and/or bioactive alkaloids and polyhydroxylated alkaloids are presented.
Stereo- And enantioselective synthesis of acetylenic 2-amino-1,3-diol stereotriads
Voituriez, Arnaud,Perez-Luna, Alejandro,Ferreira, Franck,Botuha, Candice,Chemla, Fabrice
supporting information; experimental part, p. 931 - 934 (2009/07/25)
The high-yielding and highly efficient stereoselective synthesis of enantiopure anti,anti and syn,anti acetylenic 2-amino-1,3-diol stereotriads from α-alkoxy-tert-butanesulfinylimines bearing a stereocenter α to the imino group is reported. The stereosele
