1114501-60-8

Basic information

• Product Name: 3-methyl-2-pyridyl phenyl selenide
• Synonyms: 3-methyl-2-pyridyl phenyl selenide
• CAS NO: 1114501-60-8
• Molecular Formula: C₁₂H₁₁NSe
• Molecular Weight: 248.18
• Mol File: 1114501-60-8.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-methyl-2-pyridyl phenyl selenide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyl-2-pyridyl phenyl selenide(1114501-60-8)
• EPA Substance Registry System: 3-methyl-2-pyridyl phenyl selenide(1114501-60-8)

Safety Data

• Hazardous Substances Data: 1114501-60-8(Hazardous Substances Data)

Upstream product

• 3430-17-9 2-bromo-3-picoline 
• 1132-39-4 diphenylselenide 
• 1666-13-3 diphenyl diselenide 

Relevant articles and documents

Syntheses, characterization, and single crystal X-ray analysis of 2-pyridyl aryl selenium (IV) bromides and chlorides

In the present work, a variety of symmetrical and unsymmetrical 2-pyridyl aryl selenium (IV) chlorides or bromides were prepared by the dropwise addition of a dilute solution of bromine or sulfuryl chloride to the corresponding 2-pyridyl aryl selenide in dried organic solvent with continuous stirring at 0 °C. Removal of the solvent under reduced pressure resulted in the synthesis of, 2-pyridyl aryl selenium (IV) bromides or chlorides, respectively, in quantitative yields. The titled dihalides prepared were characterized by elemental analysis, spectroscopic studies, and single crystal X-ray analysis. Single crystal X-ray analysis revealed that the 2-pyridyl aryl selenium (IV) bromides/chlorides have a distorted trigonal bipyramidal structure. The pyridyl and phenyl rings along with a lone pair of electrons on selenium are at equatorial positions whereas chloride/bromide atoms at axial positions of the distorted trigonal bipyramidal structure.