111454-05-8Relevant academic research and scientific papers
ELECTROCHEMISTRY OF SELF-COMPLEXATION. I. ELECTROCHEMISTRY OF PICRYL SERIES SELF-COMPLEXATION
Bumin, K. P.,Il'ina, I. G.,Moiseeva, A. A.,Reutov, O. A.
, p. 155 - 159 (2007/10/02)
The contribution of self-complexed molecular fragments to the total imtramolecular contact charge transfer between fragments of self-complexed molecules ("contact transfer") was studied by the electrochemical behavior of picryl series compounds and their mono- and dinitro analogs as well as the amines used in their synthesis.In contrast to reduction potentials the self-complexing oxidation potentials were highly dependent on the type of donor fragment.Based on a comparisonof the oxidation potentials of compounds of the trinitrophenyl and dinitrophenyl series containing the same donor fragment we proposed a formula for evaluating the contribution of the contact charge transfer to direct bonding, according to which it was no more than 10percent.
