1114547-93-1Relevant articles and documents
Synthesis of (Z)-1-aza-1,3-enynes by the cross-coupling of terminal alkynes with isocyanides catalyzed by rare-earth metal complexes
Zhang, Wen-Xiong,Nishiura, Masayoshi,Hou, Zhaomin
supporting information; experimental part, p. 9700 - 9703 (2009/05/30)
(Chemical Equation Presented) Rare reactivity: A binuclear catalyst intermediate leads to the Z-selective cross-coupling of terminal alkynes with isocyanides to exclusively yield the (Z)-1-aza-1,3-enyne products for the first time (see scheme).